This study examined the Use of library resources by secondary schools in Esan Central Local Government Area of Edo State. To guide this study, five research questions were raised. The purposive sampling techniques was adopted by the researcher to select 200 respondents for the study. Questionnaire was formulated and equal number was administered to the respondents so as to generate data for the study. The data gathered was analyzed using tables and simple percentage. The findings revealed that Current curriculum text books, dictionaries, fictions, computers devices, journals are available in the school library, teachers in secondary schools often use the available resources so as to meet the curriculum requirement. Library resources are being utilized in order to improve the school curriculum. Lack of fund, lack of proper organization of the school library, constant power outage, poor attitude of the staff, lack of professional trained staff are the problems militating against the availability and use of library resources. It was recommended that teaching staff and library staff should collaborate to ensure that library resources along with electronic resources are appropriately used by the students. The researcher also recommends that adequate resources should be provided information so as to improve the use of library.